the zune software is very simple to use
IMO....
all you have to do is add that music folder to the "monitored folder" section in the zune software and evrytime you add a cd rip or a music file the software will auto add it to your collection (and it downloads the album art and meta data info(this is optional tho.
but the best thing about the zune software is that there are many ways to make/manage your playlists
for ex i have a playlist called new muzik and evry time a add a new album or songs the software auto adds it to the playlist and after four days the song gets deleted off the playlist but is still on the device
here my advice to you download the software and start setting up your music,pictures,podcast,videos etc and due to this you will get more familiar with the software and settings