I just listen to it all the way through. I don't really see anything special about it. The only song I would listen to again is Death Cab For Cutie's 'Meet Me On The Equinox, Which I've had since the single was released. They are intentionally going for a Gritty Indy feel with this album, Which I do expect to go well with the movie.
But what I really like about the Twilight soundtrack is how much of a contrast there is between songs. Only 3 or 4 of the songs were Made or Mixed for the movie, with the rest being songs that have been around a while. And something special happens when you can find an already great song and inject it into a scene where it just clicks and flows. The use of Full Moon at the beginning of Twilight comes to mind. Even Super Massive Black Hole worked well during the baseball scene... When the music is made with specific scenes in mind - its just not the same. Which is the case with the New Moon soundtrack (
IMO).